13ACC

Symposia

Some symposia will be held along with different sessions

1ST CHINA/UK SYMPOSIUM ON MEDICINAL CHEMISTRY Time: September 15, 2009 Place: 3C+3D (SHICC) Chair: Dr Alejandra Palermo FRSC Manager, International Projects Royal Society of Chemistry Burlington House, Piccadilly, London W1J OBA Phone +44 (0)20 7440 3336 Fax +44 (0)20 7437 8883 mobile +44 (0)7825 186 326 Email: palermoa@rsc.org	CHEMICAL SENSORS Time: September 15, 2009 Place: 5F (SHICC) Chair: Xuhong QIAN, Prof., Ph. D., FRSC President, East China University of Science and Technology 130 Meilong Rd. Shanghai 200237, China Email: xhqian@ecust.edu.cn Co-chair: Prof. Kazuya Kikuchi Osaka University Email: kkikuchi@mls.eng.osaka-u.ac.jp Assistant Chair: Prof. Yi XIAO Dalian University of Technology Email: xiaoyi@chem.dlut.edu.cn	RECENT TOPICS IN ORGANOMETALLICS Time: September 14, 2009 Place: 3C+3D (SHICC) Organizers: Tamotsu Takahashi, Hokkaido University Catalysis Research Center Hokkaido University TEL: +81-11-706-9149 FAX: +81-11-706-9150 E-mail: tamotsu@cat.hokudai.ac.jp Yasushi Nishihara, Okayama University Yanzhong Li, East China Normal University Fu-Yu Tsai, National Taipei University of Technology

MICROSCALE CHEMISTRY ADVANCES IN PESTICIDE APPLICATION FOR CROPS

Part 1 (Sponsored by FACS) Workshop in Microscale Chemistry Experiments Time: September 15, 2009 Place: 3G (SHICC) Organisers: Prof. Zuriati Zakaria Kebangsaan University, Malaysia Secretary General, FACS Email: zuriatiz@gmail.com Dr. Supawan Tantayanon Director of Low-cost Instrumentation and Microscale Chemistry, FACS Email: supawan.t@chula.ac.th Prof. Ninghuai Zhou Director, Chinese Microscale Chemistry Centre Hangzhou Normal University Tel: 86-571-88972919 Email: cmlc28@gmail.com	Part 2 (Sponsored by UNESCO and CCS) UNESCO-China Workshop on Microscience Experiments for Science Education Time: September 16, 2009 Place: 3G (SHICC) Organisers: Maria Liouliou Project coordinator UNESCO, Natural Sciences Sector Division of Basic and Engineering Sciences Tel: 00331 4568 3813, Fax: 00 331 4568 5821 Email: m.liouliou@unesco.org Mr. A. Pokrovsky Representative of UNESCO Prof. Ninghuai Zhou Director, Chinese Microscale Chemistry Centre Hangzhou Normal University Tel: 86-571-88972919 Email: cmlc28@gmail.com	p Time: September 16, 2009 Place: 5F (SHICC) Organisers: pProf. Barry Noller University of Queensland 39 Kessels Road Coopers Plains QLD 4108, Australia Phone: +61-7 3274 9221 FAX: +61-7 3274 9003 Email: b.noller@uq.edu.au Prof. Guangfu Yang College of Chemistry Central China Normal University Email: gfyang@mail.ccnu.edu.cn



CHEMICAL SENSORS	MICROSCALE CHEMISTRY

Introduction: Chemosensors have been extensively applied to sensing and imaging of trace-amount of chemical substances. Fluorescent chemosensors offer distinct advantages in terms of high sensitivity, simplicity and real-time response. In recent years, the area of fluorescent chemosensors, featuring multidiscipline interaction, has advanced very fast and has attracted much attention. During development of fluorescent chemosensors, the knowledge of supramolecular chemistry is frequently used to design various artificial receptors; Different photophysical mechanisms, such as photoinduced electron transfer and energy transfer etc., are flexibly utilized to transfer the molecular recognition events into fluorescence signals; Furthermore, nowadays, the fluorescent sensing materials are not confined in organic fluorescent molecular probes, but become more and more plentiful: polymers, nanoparticles, fluorescent proteins etc., play increasingly important roles. The progress in the fields of fluorescent chemosensors will promote the advances in life science and environment science. In this field, great contributions have been made by Asian scientists. Many high-efficiency and practically usable fluorescent chemosensors have been developed, based on creative ideas. The 13th ACC symposium on chemosensors will focus on the latest development in the area of fluorescent chemosensors. This symposium will provide a forum for the scientists interested and working in the area of fluorescent chemosensors to review and assess the current knowledge, to exchange and co-fertilizer new ideas, and to define the scientific problems that require intensified effort. 10:30-10:35 Opening Remarks Prof. Xuhong Qian, East China University of Science and Technology 10:35-12:00 Session 1 Chaired by Prof. Kazuya Kikuchi, Osaka University Report 1 (30min): Optoelectronic Polydiacetylene Chemosensors By Prof. Dong June Ahn, Korea University Report 2 (30min): Conjugated Polyelectrolyte Probes for Biomacromolecular Detection By Prof. Shu Wang, Institute of Chemistry, CAS Report 3 (15min): Micro- and Nano-scale Tools for Biomolecular Sensing By Prof. Xingyu Jiang, CAS Key Lab for Biological Effects of Nanomaterials and Nanosafety 13:00-14:00 Session 2 Chaired by Prof. Deqing Zhang, Institute of Chemistry, CAS Report 4 (30min ): Recent Progress on Fluorescent Chemosensors By Prof. Juyoung Yoon, Ewha Womans University Report 5 (15min ): Self-assembly of Cerium-based Metal-Organic Tetrahedrons for Selectively Luminescent Sensing Natural Carbohydrates By Prof. Chunying Duan, Dalian University of Technology Report 6 (15min): Fluorescent Sensors for Zinc and Imaging in Living Cells By Prof. Hua Jiang, Institute of Chemistry, CAS 14:00-15:00 Session 3 chair: Prof. Engin U Akkaya, Bilkent University Report 7 (30min): Novel Fluorescent Sensors for Diagnosis in Solid Tumor By Prof. Yufang Xu, East China University of Science and Technology Report 8 (15min): New organic functional molecules for chemo/bio-sensors By Prof. Deqing Zhang, Institute of Chemistry, CAS Report 9 (15min): Tuning the Luminescence Lifetime of Ruthenium (II) Polypyridine Complexes and its Application in Luminescence Oxygen Sensing By Prof. Jianzhang Zhao, Dalian University of Technology 15:00-15:15 break 15:15-16:00 Session 4 Chaired by Prof. Juyoung Yoon, Ewha Womans University Report 10 (30min ): Doubly Dye-Labeled Nucleotide: Toward Efficient RNA Imaging By Prof. Akimitsu Okamoto, RIKEN Advanced Science Institute Report 11 (15min): Development of Molecular Imaging Probes with Tunable Chemical Switches for Biological Applications By Prof. Kazuya Kikuchi, Osaka University 16:00-16:50 Session 5 Chaired by Prof. Xuhong Qian, East China University of Science and Technology Report 12 (30min): Fluorescent Chemosensor for Phosphate Anion Derivatives of Biological Significance By Prof. Itaru Hamachi, Kyoto University Report 13 (15min): Fluorescent chemosensors derived from versatile Bodipy chemistry By Prof. Engin U Akkaya, Bilkent University 16:50 Concluding Remarks (Prof. Kazuya Kikuchi, Osaka University)		Part 1: Workshop in Microscale Chemistry Experiments A. Small-lab Kit for Organic Chemistry (2 hrs.) Assoc. Prof. Supawan Tantayanon (Chulalongkorn University, Bangkok, Tailand) Prof. Datin Dr. Zuriati Zakaria (University Kebangsaan University, Malaysia) This workshop will demonstrate the more practical and safer organic laboratory using Small-Lab Kit, designed and tested by chemists in Thailand, which promotes the reduction of exposure by reducing the amounts of chemicals and solvents in each experiment. Additionally, the design of the aluminum heat dissipation block eliminates the use of any potentially flammable heating sources and provides other facilities, like melting point determination and several sizes of heating mantles in it. An added benefit of Small-Lab Kit is the inclusion of all basic laboratory accessories, for examples, apparatus assembling tools and water cooling system. Moreover, a vacuum filtration using a hand pump has been introduced which make it more practical to do organic experiments. Overall, the Small-Lab Kit can be used at any place even though there is no formal laboratory available. With such a useful set of equipment, all the basic organic experiments as well as a wide range of organic reactions can be carried out. The course consists of the followings: A brief introduction to small scale chemistry Introducing a Small-Lab Kit Experiments in organic small scale chemistry Basic organic laboratory – sublimation, distillation, m.p. & b.p. determination. Organic reaction experiments – hydrolysis, esterification, condensation B. Hands-On Microscale Chemistry Workshop (1.5hrs.) ---Some Typical Expts. by Using Micro Plastic Kit--- The Chinese Approach Assoc. Prof. Yijian ZHANG & Prof. Ning-Huai Zhou Chinese Microscale Chemistry Center, Hangzhou Normal University ,Hangzhou, China The micro –plastic apparatus (kits) consists of multi-functional pipettes, 6-holes well plate and its lids with two connective tubes, 9-holes well plate, syringe, tip, LED, electrode, wires with ctocodile clips and a stand . It is novel kits with some creative parts and with low cost but very effective in conducting microscale experiments in general chemistry for high school and university level. In this workshop, the attendees will have hand on experience for some typical experiments, using the kits. The contents of the experiments are as follows: 1. The determination of indicator’s pH range 2. Preparation of Cu(NH₃)₄SO₄ 3. Micro-Titration 4. Electrolysis of Water and Explosion of Hydrogen and Oxygen 5. Voltaic Cell 6. Electrolysis of KI Solution 7. Fuel Cell 8. Preparation and Properties of C₂H₂ 　 This workshop is partially sponsored by Low-cost Instrumentation and Microscale Chemistry Network, Federation of Asian Chemical Societies. 　 Part 2: UNESCO-China Workshop on Microscience Experiments Speaker Affiliation Title *Mr. A. Pokrovsky UNESCO* GLOBAL MICROSCIENCE EXPERIMENTS PROJECT Prof. Ning Huai Zhou** Chinese Microscale Chemistry, Hangzhou Normal University, China THE STUDY AND DEVELOPMENT OF MICROCHEMISTRY IN CHINA Mr. K. M. Chan, Hongkong Micro chem. Lab Innovative Qualitative and Quantitative Instruments for Micro-scale School Chemistry Experiments Prof. Norita. Mohamed University Sains, Malaysia Microscale Chemistry Innovations in Malaysia Prof. Guo[pen YAN Wuhan Instituite of Technology, Wuhan, China THE MICRO-BURET FOR ACID-BASE TITRATION AND MOHR TITRATION Ms. CHEONG Wai Man Macao Pui Ching Middle School Microscale Titration Dr. KHURMA, Jagjit R., Technology and Environment University of the South Pacific Suva, Fiji Islands A microscale experiment for the determination of enthalpy change and entropy change from temperature dependence of equilibrium constant Prof. Dr. Fortunato B. Svilla, University of Santo Tomas, Manila, Philippins Microscale Experiments Based on a Low-cost Electronic Thermometer Porf. Xiaoxue XU Chongqing Educational Research Academy, China Innovating on Microscale Instrument Dr. Teruo YOSHINO, International Christian University, Japan Effective Chemical Education by Microscale Chemistry Experimets for High School and University Mr.En ZHU, Huipu High School, Linhai, Zhejiang 317000, China Practices on MCE in Secondary Schools Prof. CHIN-HSIANG FANG, Tajen University, Pingtund, Taiwan, China Demonstration of Microscale Chemistry Experiments in Taiwan Assoc. Prof. Lan TAO, Hangzhou Normal University, Hangzhou, China THE GLASSWTARE FOR MICROSCALE CHEMISTRY Mr. WANG Hui, Nanhui High School,201300 Shanghai, China Two Microscale Chemistry Experiments in High School

Advances in Pesticide Application for Crops 1^st Session chaired by Professor Barry Noller 10：30-10：55：Dr Greg Simpson “Australia and the emerging Bioeconomy” 10：55-11：20：Professor Ivan Kennedy “ Catchment-scale ecological risk assessment of pesticides” 11：20~11：45：Dr Gary Dorr “Understanding the spraying process to maximise benefit and minimise risk from pesticide use” 2^nd Session chaired by Dr Greg Simpson 14：00-14：25：Dr Shuo Wang “Rapid immunochemical tests as tools for environmental management of agrochemicals” 14：25-14：50：Prof. Guangfu Yang “Computational simulations in pesticide discovery” 14：50-15：15：Professor Barry Noller “Pesticide Monitoring in the Paddy Field Ecosystem, Thailand and outcomes” 15：15-15：40：Prof. Zhen Xi “Structural insight into unique properties of protoporphyrinogen oxidase from Bacillus subtilis” 3^rd Session chaired by Professor Guangfu Yang 16：00-16：25：Prof. Zhong Li “Molecular design, bioactivities and modes of action of neonicotinoids with cis-configuration” 16：25-16：50：Prof. Jinfeng Dong “Low energy preparation for water-based nano pesticide formulations ” 16：50-17：05：Dr. Greg Simpson “Chemistry for a sustainable world - An overview”




Chairman of 13th ACC: Prof. Chunli Bai (President, Chinese Chemical Society)		13th ACC Secretariat: Prof. Long Lu, Secretary General, 13 th ACC Shanghai Institute of Organic Chemistry 354 Lingling Rd, Shanghai, China, 200032 Tel: +86-21-54925210, +86-21-54925209 Fax: +86-21-64166128 E-mail: secretariat@13acc.org





1ST CHINA/UK SYMPOSIUM ON MEDICINAL CHEMISTRY 　 Sponsor: the Royal Society of Chemistry the Chinese Chemical Society the Chinese Pharmaceutical Association Speakers: Prof. Jiandong Jiang (Inst. Medicinal Biotechnology, Chinese Academy of Medical Science, China) Prof. Hualiang Jiang (Shanghai Institute of Materia Medica, CAS, China) Prof. Yang Ye (Shanghai Institute of Materia Medica, CAS, China) Prof. Dawei Ma (Shanghai Institute of Organic Chemistry, CAS, China) Prof. Linxiang Zhao (Shenyang Pharmaceutical University, China) Prof. Steven V. Ley (Chemistry Department, Cambridge University, UK) Dr Min Zhang (Senior Vice President, Biotica Technology Ltd., UK) Dr David Rees (Vice President Medicinal Chemistry, Astex, UK) Dr Anthony Wood (Vice President, Head of Discovery Chemistry, Pfizer, UK) Professor Paul O’Neill (Chemistry Department, Liverpool University, UK) Organising Committee Dr David Alker (President Industrial Forum, RSC) Prof Chen Kaixian (Shanghai Institute of Materia Medica, CAS) Dr Alejandra Palermo (Manager, International Projects, RSC) Dr David Rees (Astex and President Elect RSC Organic Division) Dr Ming Qiang Zhang (Biotica Technological Ltd) Prof Zhang Lihe (School of Pharmaceutical Sciences, Beijing University) Prof Long Lu (Shanghai Institute of Organic Chemistry and CCS) Mrs Gwen Jones (Publishing, RSC)		RECENT TOPICS IN ORGANOMETALLICS Chairperson: Prof. Yasushi Nishihara (Okayama University) 13:00 Opening Remarks Prof. Tamotsu Takahashi (Hokkaido University) 13:05 Prof. Chanjuan Xi (Tsinghua University) “Metal-phosphorus Reaction of Unsaturates and Their Applications” 13:25 Prof. Jwu-Ting. Chen (National Taiwan University) “Kinetics & Mechanism of the Ethylene/Norbornene Alternating Copolymerization Catalyzed by Cationic Organopalladium” 13:45 Prof. Yuanhong Liu (Shanghai Institute of Organic Chemistry) "Versatile Reaction Modes of a-Alkynyl- or -Alkenyl-Zirconacycles Derived by Zirconocene Coupling Reactions with 1,3-Butadiynes and Enynes" 14:05 Prof. Ruimao Hua (Tsinghua University) “Transition Metal-Catalyzed Stereocontrollable Semi-reduction of Internal Alkynes” 14:25 Prof. Guohua Gao (East China Normal University) “Synthesis of Phenylene Ethynylene Oligomers by Ppalladium Catalyzed Coupling Reactions". 14:45 Prof. Huanfeng Jiang (South China University of Technology) “Palladium-Catalyzed Oxidative Reactions of Alkynes or Alkenes with Molecular Oxygen.” 15:05-15:30 Break Chairperson: Prof. Yanzhong Li (East China Normal University) 15:30 Prof. Ken Tanaka (Tokyo University of Agriculture) “Rh Catalyzed [2+2+2] Cycloadditions for the Synthesis of Functional Aromatic Compounds” 15:50 Prof. Chunming Cui (Nankai University) “Dehydrohalogenation to Silylenes". 16:10 Prof. Yasushi Nishihara (Okayama University) "Highly Efficient and Selective Synthesis of Anticancer Agent Tamoxifen Mediated by a Zirconocene Complex" 16:30 Prof. Jianbo Wang (Peking University) “Pd-Catalyzed Reaction of Diazo Compounds” 16:50 Prof. Noriyuki Suzuki (Sophia University) “New Aspects in Transition Metal Complexes of [5]Cumulenes” 17:10 Prof. Zhenfeng Xi (Peking University) “Oxy-cyclopentadienyl (OCp) Dianions: Facial Synthesis, Structural Characterization and Synthetic Applications” 17:30 Prof. Tamotsu Takahashi (Hokkaido University) “Zirconium Catalyzed Halogen Exchange Reaction of Alkyl Halides” 17:50 Closing Remarks Prof. Yasushi Nishihara (Okayama University)